{"id":84335,"date":"2021-01-29T07:35:55","date_gmt":"2021-01-29T06:35:55","guid":{"rendered":"https:\/\/renewable-carbon.eu\/news\/?p=84335"},"modified":"2021-09-09T21:12:30","modified_gmt":"2021-09-09T19:12:30","slug":"new-electrode-design-more-efficiently-converts-co2-into-fuel","status":"publish","type":"post","link":"https:\/\/renewable-carbon.eu\/news\/new-electrode-design-more-efficiently-converts-co2-into-fuel\/","title":{"rendered":"New electrode design more efficiently converts CO2<\/sub> into fuel"},"content":{"rendered":"

For years, researchers have worked to repurpose excess atmospheric carbon dioxide into new chemicals, fuels and other products traditionally made from hydrocarbons harvested from fossil fuels. The recent push to mitigate the climactic effects of greenhouse gases in the atmosphere has chemists on their toes to find the most efficient means possible. A new study introduces an electrochemical reaction, enhanced by polymers, to improve CO2<\/sub>-to-ethylene conversion efficiency over previous attempts. \u00a0<\/strong><\/p>\n

\"AGewirth2021\"
Photo by L. Brian Stauffer – Professor Andy Gewirth, left, and graduate student Stephanie Chen<\/figcaption><\/figure>\n

The results of the study led by University of Illinois Urbana-Champaign\u00a0chemistry\u00a0professor\u00a0Andrew Gewirth\u00a0and graduate student Xinyi (Stephanie) Chen are published in the journal Natural Catalysis<\/em><\/a>.<\/p>\n

Allowing CO2<\/sub> gas to flow through a reaction chamber fitted with copper electrodes and an electrolyte solution is the most common method researchers use to convert CO2<\/sub> to useful carbon-containing chemicals, the study reports.<\/p>\n

\u201cCopper metal is highly selective toward the type of carbon that forms ethylene,\u201d Gewirth said. \u201cDifferent electrode materials will produce different chemicals like carbon monoxide instead of ethylene, or a mix of other carbon chemicals. What we have done in this study is to design a new kind of copper electrode that produces almost entirely ethylene.\u201d<\/p>\n

Previous studies have used other metals and molecular coatings on the electrode to help direct the CO2<\/sub>-reduction reactions, the study reports. However, these coatings are not stable, often break down during the reaction process and fall away from the electrodes.<\/p>\n

\u201cWhat we did differently in this study was to combine the copper ions and polymers into a solution, then apply that solution to an electrode, entraining the polymer into the copper,\u201d Chen said.<\/p>\n

In the lab, the team found that the new polymer-entrained electrodes were less likely to break down and produced more stable chemical intermediates, resulting in more efficient ethylene production. \u201cWe were able to convert CO2<\/sub> to ethylene at a rate of up to 87 percent, depending on the electrolyte used,\u201d Chen said. \u201cThat is up from previous reports of conversion rates of about 80 percent\u00a0using other types of electrodes.\u201d<\/p>\n

\u201cWith the development of economic sources of electricity, combined with the increased interest in CO2<\/sub>-reduction technology, we see great potential for commercialization of this process,\u201d Gewirth said.<\/p>\n

The International Institute for Carbon Neutral Energy Research, Shell\u2019s New Energy Research and Technology and the National Science Foundation supported this research.<\/p>\n

Gewirth also is affiliated with the Materials Research Laboratory at Illinois.<\/p>\n

 <\/p>\n

The paper \u201cElectrochemical CO2-to-ethylene conversion on polyamine-incorporated Cu electrodes\u201d is available\u00a0online\u00a0and from the\u00a0U. of I. News Bureau. DOI: 10.1038\/s41929-020-00547-0<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

For years, researchers have worked to repurpose excess atmospheric carbon dioxide into new chemicals, fuels and other products traditionally made from hydrocarbons harvested from fossil fuels. The recent push to mitigate the climactic effects of greenhouse gases in the atmosphere has chemists on their toes to find the most efficient means possible. A new study […]<\/p>\n","protected":false},"author":59,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_seopress_robots_primary_cat":"","nova_meta_subtitle":"","footnotes":""},"categories":[5571],"tags":[10744,12366,10408,10743],"supplier":[150],"class_list":["post-84335","post","type-post","status-publish","format-standard","hentry","category-co2-based","tag-carboncapture","tag-fuels","tag-greenchemistry","tag-useco2","supplier-university-of-illinois"],"_links":{"self":[{"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/posts\/84335","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/users\/59"}],"replies":[{"embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/comments?post=84335"}],"version-history":[{"count":0,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/posts\/84335\/revisions"}],"wp:attachment":[{"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/media?parent=84335"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/categories?post=84335"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/tags?post=84335"},{"taxonomy":"supplier","embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/supplier?post=84335"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}