{"id":43327,"date":"2017-06-02T07:29:26","date_gmt":"2017-06-02T05:29:26","guid":{"rendered":"https:\/\/renewable-carbon.eu\/news\/?p=43327"},"modified":"2017-05-31T14:49:31","modified_gmt":"2017-05-31T12:49:31","slug":"green-plastics-from-citrus-fruit-peels-and-sugar","status":"publish","type":"post","link":"https:\/\/renewable-carbon.eu\/news\/green-plastics-from-citrus-fruit-peels-and-sugar\/","title":{"rendered":"Green plastics from citrus fruit peels and sugar"},"content":{"rendered":"<p>The need for bio-plastics is growing. Brand owners are looking for sustainable solutions for packaging, fibres, paints, inks and plastics.<\/p>\n<p>This creates a need for high-performance bio-plastics such as polyamides (PA) and polyesters (PET).<\/p>\n<p>The total global production of PET polymers was over 50 MT and that of PA over 10 MT in 2015. Furan dicarboxylic acid (FDCA) -based polyethylene furanoate (PEF) polymers offer a bio-based alternative to petroleum-based PET polymers.<\/p>\n<p>Polyamides are used in applications calling for high durability and strength. Muconic acid is a versatile monomer which can be converted to multiple PA monomers such as adipic acid, terephthalic acid, hexamethylene diamine, caprolactam, caprolactone and 1,6-hexanediol. Polyamides (PA) are used as engineering plastics, for example in automobiles.<\/p>\n<p>New prospects for the use of pectin<\/p>\n<p>VTT has developed a process to convert pectin biochemically to an aldaric acid, which in turn can be chemically converted to monomers for bio-based polyesters and polyamides. Pectin is a side stream obtained from citrus fruit peels or from sugar beet pulp.<\/p>\n<p>Sugar beet pulp is currently used as animal feed, but the goal is to use the pulp for higher-value applications. Pectin is currently underutilized as the production is only about 40 000 t\/a, with the potential of several tens of million tonnes available annually. Its current use is in the food and beverage industry as, for example, a gelling agent. In addition to pectin, wood- or plant-based glucose can be used in the production of aldaric acid.<\/p>\n<p>Competitive new technology<\/p>\n<p><a href=\"http:\/\/www.vttresearch.com\/media\/news\/a-new-method-for-producing-plant-based-drinking-bottles-from-fdca\" target=\"_blank\">VTT has patented a technology<\/a> combining biotechnical and chemical reaction steps to produce FDCA and muconic acid from aldaric acids. The first step consists of the oxidation of galacturonic acid, a constituent of pectin, to galactaric acid with a fungal biocatalyst. The conversion efficiency is high and this step has been scaled up to pilot scale (300 l) delivering kilogramme amounts of galactaric acid for the second step conversion.<\/p>\n<p>The second step converts the aldaric acid into furan carboxylic acid (FCA) and FDCA or muconic acid depending on the reaction conditions. FDCA is a monomer for polyethylene furanoate (PEF), a bio-based alternative for polyethylene terephthalate (PET). Muconic acid is a precursor for polyamide monomers.<\/p>\n<p>The techno-economic analysis shows competitive pricing and the life cycle analysis shows that the carbon foot print is lower compared to petroleum-based alternatives for both monomers.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>The need for bio-plastics is growing. Brand owners are looking for sustainable solutions for packaging, fibres, paints, inks and plastics. This creates a need for high-performance bio-plastics such as polyamides (PA) and polyesters (PET). The total global production of PET polymers was over 50 MT and that of PA over 10 MT in 2015. Furan [&#8230;]<\/p>\n","protected":false},"author":59,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_seopress_robots_primary_cat":"","nova_meta_subtitle":"","footnotes":""},"categories":[5572],"tags":[5847],"supplier":[459],"class_list":["post-43327","post","type-post","status-publish","format-standard","hentry","category-bio-based","tag-bioplastics","supplier-vtt-technical-research-centre-of-finland"],"_links":{"self":[{"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/posts\/43327","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/users\/59"}],"replies":[{"embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/comments?post=43327"}],"version-history":[{"count":0,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/posts\/43327\/revisions"}],"wp:attachment":[{"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/media?parent=43327"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/categories?post=43327"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/tags?post=43327"},{"taxonomy":"supplier","embeddable":true,"href":"https:\/\/renewable-carbon.eu\/news\/wp-json\/wp\/v2\/supplier?post=43327"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}