{"id":107929,"date":"2022-04-19T07:06:00","date_gmt":"2022-04-19T05:06:00","guid":{"rendered":"https:\/\/renewable-carbon.eu\/news\/?p=107929"},"modified":"2022-04-14T14:49:30","modified_gmt":"2022-04-14T12:49:30","slug":"new-method-purifies-hydrogen-from-heavy-carbon-monoxide-mixtures","status":"publish","type":"post","link":"https:\/\/renewable-carbon.eu\/news\/new-method-purifies-hydrogen-from-heavy-carbon-monoxide-mixtures\/","title":{"rendered":"New method purifies hydrogen from heavy carbon monoxide mixtures"},"content":{"rendered":"\n\n\n

Refining metals, manufacturing fertilizers and powering fuel cells for heavy vehicles are all processes that require purified hydrogen. But purifying, or separating, that hydrogen from a mix of other gases can be difficult, with several steps. A research team led by Chris Arges, Penn State associate professor of chemical engineering, demonstrated that the process can be simplified using a pump outfitted with newly developed membrane materials.<\/strong><\/p>\n\n\n\n

\"Chris
Chris Arges (right), Penn State associate professor of chemical engineering, proposes using high-temperature proton-selective polymer electrolyte membranes, or PEMs, to separate hydrogen from other gases in an ACS Energy Letters paper. Co-author Deepra Bhattacharya, Penn State doctoral student in chemical engineering, is seen at left.\u00a0
\u00a9\u00a0Kelby Hochreither\/Penn State.<\/figcaption><\/figure><\/div>\n\n\n\n

The researchers used an electrochemical hydrogen pump to both separate and compress hydrogen with an 85% recovery rate from fuel gas mixtures known as syngas and 98.8% recovery rate from conventional water gas shift reactor exit stream \u2014 the highest value recorded. The team detailed their approach in\u00a0ACS Energy Letters<\/em><\/u><\/a>.\u00a0<\/p>\n\n\n\n

Traditional methods for hydrogen separations employ a water gas shift reactor, which involves an extra step, according to Arges. The water gas shift reactor first converts carbon monoxide into carbon dioxide, which is then sent through an absorption process to separate the hydrogen from it. Then, the purified hydrogen is pressurized using a compressor for immediate use or for storage.<\/p>\n\n\n\n

The key, Arges said, is to use high-temperature, proton-selective polymer electrolyte membranes, or PEMs, which can separate hydrogen from carbon dioxide and carbon monoxide and other gas molecules quickly and cost-effectively. The electrochemical pump, equipped with the PEM and other new materials Arges developed, is more efficient than conventional methods because it simultaneously separates and compresses hydrogen from gas mixtures. It also can operate at temperatures of 200 to 250 degrees Celsius \u2014 20 to 70 degrees higher than other high-temperature-PEM-type electrochemical pumps \u2014 which improves its ability to separate hydrogen from the unwanted gasses. <\/p>\n\n\n\n

\u201cThis is an effective and potentially cost saving way to purify hydrogen, especially when there is a large carbon monoxide content,\u201d Arges<\/strong> said. \u201cNo one has ever purified hydrogen to this extent with a gas feed that contained more than 3% of carbon monoxide using an electrochemical hydrogen pump, and we achieved it with mixtures that consist of up to 40% carbon monoxide by using a relatively new class of high-temperature PEM and electrode ionomer binder materials.\u201d<\/p><\/blockquote>\n\n\n\n

To carry out the separation, Arges\u2019 team created an electrode \u201csandwich,\u201d where electrodes with opposing charges form the “bread” and the membrane is the “deli meat.” The electrode ionomer binder materials are designed to keep the electrodes together, like the gluten of the bread.<\/p>\n\n\n\n

\"Arges
Arges has two U.S. patent applications pending on components used in this research: One on high-temperature PEMs, and the other on the electrochemical hydrogen pump using the high-temperature PEMs and phosphonic acid ionomer electrode binder.\u00a0\u00a9<\/strong><\/strong> Kelby Hochreither\/Penn State.<\/strong><\/figcaption><\/figure><\/div>\n\n\n\n

In the pump, the positively charged electrode, or bread slice, breaks down the hydrogen into two protons and two electrons. The protons pass through the membrane, or deli meat, while the electrons travel externally through the pump using a wire that touches the positively charged electrode. The protons then travel through the membrane to the negatively charged electrode and recombine with the electrons to re-form the hydrogen.<\/p>\n\n\n\n

The PEM works by permitting the passage of protons but preventing the larger molecules of carbon monoxide, carbon dioxide, methane and nitrogen from coming through, according to Arges. For the electrodes to work effectively in the hydrogen pump, Arges and his team synthesized a special phosphonic acid ionomer binder that acts as an adhesive to keep the electrode particles together. <\/p>\n\n\n\n

\u201cThe binder is effective for making a mechanically robust, porous electrode that permits gas transport so hydrogen can react on the electrocatalyst surface while also shuttling protons to and from the membrane,\u201d Arges<\/strong> said.\u00a0<\/p><\/blockquote>\n\n\n\n

The researchers plan to investigate how their approach and tools will aid in purifying hydrogen when stored in existing natural gas pipelines. Distributing and storing hydrogen in this manner has never been accomplished, but holds great interest, according to Arges. He explained that hydrogen could aid in generating electric power via a fuel cell or turbine generator to support solar or wind energy-based systems and a variety of more sustainable applications. <\/p>\n\n\n\n

\u201cThe challenge is that hydrogen has to be stored at low concentrations in the pipeline \u2014 less than 5% \u2014 because it can degrade the pipeline, but end-use applications require more than 99% pure hydrogen,\u201d Arges said. <\/p><\/blockquote>\n\n\n\n

Arges filed two U.S. patent applications on components used in this research while he was on faculty at Louisiana State University. One is on high-temperature PEMs, and the other is on the electrochemical hydrogen pump using the high-temperature PEMs and phosphonic acid ionomer electrode binder. He is currently licensing the technology for a start-up company he co-founded with his wife, Hiral Arges, called Ionomer Solutions LLC<\/u><\/a>. <\/p>\n\n\n\n

Deepra Bhattacharya, Penn State doctoral student in chemical engineering, co-authored the paper. Other contributors include Gokul Venugopalan, postdoctoral researcher in the Chemistry and Nanoscience Research Center at the National Renewable Energy Laboratory in Golden, Colorado, and former doctoral student of Arges; and Evan Andrews, Luis Briceno-Mena, Jos\u00e9 Romagnoli and John Flake, chemical engineering researchers from Louisiana State University.   <\/p>\n\n\n\n

The U.S. Department of Energy\u2019s Office of Energy Efficiency and Renewable Energy funded this work.  <\/p>\n\n\n\n

Original publication<\/h3>\n\n\n\n